α,α,α-三硝基甲苯
α,α,α-三硝基甲苯是一种有机化合物，化学式为C7H5N3O6，是三硝基甲苯的同分异构体之一。它可由α,α-二硝基苄基钾和四氧化二氮在三氯甲烷中反应得到。[2]它可以用于制备α-C-硝基腙。[3]
| α,α,α-三硝基甲苯 | |
|---|---|
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| 英文名 | (Trinitromethyl)benzene α,α,α-Trinitrotoluene |
| 别名 | (三硝基甲基)苯 |
| 识别 | |
| CAS号 | 67483-29-8 
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| SMILES |
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| 性质 | |
| 化学式 | C7H5N3O6 |
| 摩尔质量 | 227.13 g·mol−1 |
| 熔点 | 4.5 °C（277.6 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Titov, A. I.; Smirnov, V. V. Effect of complex formation, ionization, and isomerization of organic compounds on their chemical activity in nitration. Synthesis of phenyltrinitromethane and its properties. Doklady Akademii Nauk SSSR, 1952. 83. 243-246. ISSN: 0002-3264.
- ^ Makhova, N. N.; Ovchinnikov, I. V.; Dubonos, V. G.; Strelenko, Yu. A.; Khmel?nitski, L. I. New methods for preparation of nitrile oxides and the corresponding disubstituted furoxans by reaction of N2O4 with salts of substituted dinitromethanes. Izvestiya Akademii Nauk, Seriya Khimicheskaya, 1993. 1: 147-151.
- ^ Shvarts, I. Sh.; Krayushkin, M. M.; Sevost'yanova, V. V.; Yarovenko, V. N. Synthesis and properties of α-C-nitrohydrazones. 2. Reaction of hydrazines with trinitromethyl components（俄文）. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya. 1979. 5. 1069-1073.