α,α,α-三硝基甲苯
α,α,α-三硝基甲苯是一種有機化合物，化學式為C7H5N3O6，是三硝基甲苯的同分異構體之一。它可由α,α-二硝基苄基鉀和四氧化二氮在三氯甲烷中反應得到。[2]它可以用於製備α-C-硝基腙。[3]
| α,α,α-三硝基甲苯 | |
|---|---|
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| 英文名 | (Trinitromethyl)benzene α,α,α-Trinitrotoluene |
| 別名 | (三硝基甲基)苯 |
| 識別 | |
| CAS號 | 67483-29-8 
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| SMILES |
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| 性質 | |
| 化學式 | C7H5N3O6 |
| 摩爾質量 | 227.13 g·mol−1 |
| 熔點 | 4.5 °C（277.6 K）[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
編輯- ^ Titov, A. I.; Smirnov, V. V. Effect of complex formation, ionization, and isomerization of organic compounds on their chemical activity in nitration. Synthesis of phenyltrinitromethane and its properties. Doklady Akademii Nauk SSSR, 1952. 83. 243-246. ISSN: 0002-3264.
- ^ Makhova, N. N.; Ovchinnikov, I. V.; Dubonos, V. G.; Strelenko, Yu. A.; Khmel?nitski, L. I. New methods for preparation of nitrile oxides and the corresponding disubstituted furoxans by reaction of N2O4 with salts of substituted dinitromethanes. Izvestiya Akademii Nauk, Seriya Khimicheskaya, 1993. 1: 147-151.
- ^ Shvarts, I. Sh.; Krayushkin, M. M.; Sevost'yanova, V. V.; Yarovenko, V. N. Synthesis and properties of α-C-nitrohydrazones. 2. Reaction of hydrazines with trinitromethyl components（俄文）. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya. 1979. 5. 1069-1073.