硫代乙酸-S-乙酯
化合物
硫代乙酸-S-乙酯是一种有机化合物，化学式为CH3C(O)SC2H5。它可由乙酰氯和乙硫醇在氯氧化铋催化下反应制得。[2]它和碘苯、锌粉在镍盐、联吡啶催化下反应，可以得到苯甲酸-S-乙酯和苯乙硫醚。[3]
| 硫代乙酸-S-乙酯 | |
|---|---|
| |
| 识别 | |
| CAS号 | 625-60-5 
|
| PubChem | 61171 |
| ChemSpider | 55117 |
| 性质 | |
| 化学式 | C4H8OS |
| 摩尔质量 | 104.17 g·mol−1 |
| 沸点 | 114 °C[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Hawkins, Peter J.; Tarbell, D. Stanley. Studies on Model Compounds for Coenzyme A. A Kinetic Study of Aminolysis and Hydrolysis of Ethyl Thioacetate and β-Acetaminoethyl Thioacetate in Aqueous Solution. Journal of the American Chemical Society. 1953, 75 (12): 2982–2985. ISSN 0002-7863. doi:10.1021/ja01108a057.
- ^ Ghosh, Rina; Maiti, Swarupananda; Chakraborty, Arijit. Facile catalyzed acylation of heteroatoms using BiCl3 generated in situ from the procatalyst BiOCl and acetyl chloride. Tetrahedron Letters. 2004, 45 (36): 6775–6778. doi:10.1016/j.tetlet.2004.07.044.
- ^ Mai, Wen-Peng; Sui, Hong-Da; Lv, Ming-Xiu; Lu, Kui. Nickel-catalyzed carbonylation of thioacetates with aryl iodides via CO insertion and C–S bond cleavage. Journal of Chemical Research. 2021, 45 (9-10): 890–895. ISSN 1747-5198. doi:10.1177/17475198211028114.