1,2,3,4,5,6,7,8-八氢萘
1,2,3,4,5,6,7,8-八氢萘是一种有机化合物，化学式为C10H16。它可由四氢萘和锂在乙二胺溶液中反应得到。[2]4a,8a-八氢萘二酚和钾、三氯化钛在四氢呋喃中反应，也能得到该化合物。[3]它可以被过氧化氢氧化为八氢-4a,8a-环氧萘[4]或被高碘酸钠氧化为1,6-环癸二酮。[5]
| 1,2,3,4,5,6,7,8-八氢萘 | |
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| 识别 | |
| CAS号 | 493-03-8 
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| 性质 | |
| 化学式 | C10H16 |
| 摩尔质量 | 136.23 g·mol−1 |
| 密度 | 0.9170 g·cm−3（20 °C）[1] |
| 熔点 | −34 °C（239 K）[1] |
| 沸点 | 194 °C（467 K）（750 torr）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ 1.0 1.1 1.2 Huckel, Walter; Danneel, Rolf; Schwartz, Albert; Gercke, Achim. Stereochemistry of bicyclic ring systems. V. Δ9,10-Octalin. Justus Liebigs Annalen der Chemie, 1929. 474: 121-144. ISSN: 0075-4617.
- ^ Leslie Reggel, R. A. Friedel, Irving Wender. Lithium in Ethylenediamine: A New Reducing System for Organic Compounds 1. The Journal of Organic Chemistry. 1957-08, 22 (8): 891–894 [2021-04-17]. ISSN 0022-3263. doi:10.1021/jo01359a009 （英语）.
- ^ Eric Block. John Wiley & Sons, Inc. , 编. Olefin Synthesis by Deoxygenation of Vicinal Diols. Hoboken, NJ, USA: John Wiley & Sons, Inc. 1984-01-18: 457–566 [2021-04-17]. ISBN 9780471264187. doi:10.1002/0471264180.or030.02 （英语）.
- ^ Makoto Nakajima, Yuka Sasaki, Hatsue Iwamoto, Shun-ichi Hashimoto. Bipyridine N,N′-Dioxide: A Felicitous Ligand for Methyltrioxorhenium-Catalyzed Epoxidation of Olefins with Hydrogen Peroxide. Tetrahedron Letters. 1998-01, 39 (1-2): 87–88 [2021-04-17]. doi:10.1016/S0040-4039(97)10495-6 （英语）.
- ^ Carley L. Chandler, Benjamin List. Catalytic, Asymmetric Transannular Aldolizations: Total Synthesis of (+)-Hirsutene. Journal of the American Chemical Society. 2008-05, 130 (21): 6737–6739 [2021-04-17]. ISSN 0002-7863. doi:10.1021/ja8024164 （英语）.