乙基硒代磷醯二氯

乙基硒代磷醯二氯是一種有機磷化合物,化學式為C2H5Cl2PSe,它是VE硒代物selenophos英語selenophos的前體。[3]它可由氯乙烷三氯化磷三氯化鋁氮氣中加熱反應得到,或通過乙基二氯化磷加熱製得。[1]

Ethylphosphonoselenoic dichloride
IUPAC名
dichloro-ethyl-selanylidene-λ5-phosphane
識別
CAS號 14705-46-5  checkY
PubChem 518992
ChemSpider 452726
SMILES
 
  • CCP(=[Se])(Cl)Cl
性質
化學式 C2H5Cl2PSe
摩爾質量 209.9 g·mol−1
沸點 92—94 °C(365—367 K)(25 torr)[1]
38—39 °C(311—312 K)(1.5 torr)[2]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參見

編輯

參考文獻

編輯
  1. ^ 1.0 1.1 Ivin, S. Z.; Shelakova, I. D. Synthesis of dichlorides of alkylphosphonoselenoic acid. Zhurnal Obshchei Khimii. 1961, 31: 4052–4053. ISSN 0044-460X. 
  2. ^ Gryszkiewicz-Trochimowski, Eustache; Quinchon, Jean; Gryszkiewicz-Trochimowski, Oleg. Derivatives of alkylselenophosphonic acids and alkyltellurophosphonic acids. I. Prepn. of diesters of alkylselenophosphonic acids and attempts to prepare diethyl ethyltellurophosphonate. Bulletin de la Societe Chimique de France. 1960: 1794–1798. ISSN 0037-8968. 
  3. ^ Akerfeldt, Stig.; Fagerlind, Lars. Selenophosphorus Compounds as Powerful Cholinesterase Inhibitors. Journal of Medicinal Chemistry. January 1967, 10 (1): 115–116. PMID 6031689. doi:10.1021/jm00313a032.