N-乙醯基乙醯苯胺
N-乙醯基乙醯苯胺是一種有機化合物,化學式為C10H11NO2。它可由乙醯苯胺和乙醯氯[2]或乙酸酐[3]反應得到。它和勞森試劑反應,可以得到硫代乙醯苯胺。[4]它可以在HCl中重排,得到4-氨基苯乙酮。[5]
N-乙醯基乙醯苯胺 | |
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別名 | N,N-二乙醯基苯胺 |
識別 | |
CAS號 | 1563-87-7 ![]() |
性質 | |
化學式 | C10H11NO2 |
摩爾質量 | 177.2 g·mol−1 |
熔點 | 37.5 °C(310.6 K)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
參考文獻
編輯- ^ "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-10-11].
- ^ Heyns, Kurt; Pyrus, Wolfgang. Reactions of the carbonamide group. III. Reaction with organometallic compounds. Chemische Berichte, 1955. 88: 678-683.
- ^ Nagaraj R. Ayyangar, Kumar V. Srinivasan. Effect of substituents in the formation of diacetanilides. Canadian Journal of Chemistry. 1984-07-01, 62 (7): 1292–1296 [2021-10-11]. ISSN 0008-4042. doi:10.1139/v84-215 (英語).
- ^ Meyer, H. J.; Nolde, C.; Thomsen, I.; Lawesson, S. O. Preparation and some reactions of N,N-diacetylamines. Bulletin des Societes Chimiques Belges, 1978. 87 (8): 621-626.
- ^ J. F. J. Dippy, V. Moss. 411. The rearrangement of NN-diacylanilnes and the nuclear benzoylation of anilines. Journal of the Chemical Society (Resumed). 1952: 2205 [2021-10-11]. ISSN 0368-1769. doi:10.1039/jr9520002205 (英語).