三氟乙酸亚铊
三氟乙酸亚铊是一种有机酸盐，化学式为TlOCOCF3。它可由碳酸亚铊和三氟乙酸反应制得。[2]
| 三氟乙酸亚铊 | |
|---|---|
| 识别 | |
| CAS号 | 2923-19-5 
|
| 性质 | |
| 化学式 | C2F3O2Tl |
| 摩尔质量 | 317.4 g·mol−1 |
| 溶解性（水） | 易溶[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
应用
编辑它可用于制备三氟乙酸根的配合物，如它和[RhCl(C2H4)2]2在戊烷中反应，可以得到[Rh(OCOCF3)(C2H4)2]2；[3]它和[(C3H5)3WCl]2反应，可以得到(C3H5)3WO2CCF3。[4]
参考文献
编辑- ^ Swarts, F. Some trifluoroacetates. Bulletin des Societes Chimiques Belges (1939), 48, 176-191. ISSN 0037-9646
- ^ F. Albert Cotton, Naresh S. Dalal, Penglin Huang, Sergey A. Ibragimov, Carlos A. Murillo, Paula M. B. Piccoli, Chris M. Ramsey, Arthur J. Schultz, Xiaoping Wang, and Qinliang Zhao. Better Understanding of the Species with the Shortest Re26+ Bonds and Related Re27+ Species with Tetraguanidinate Paddlewheel Structures. Inorg. Chem. 2007, 46, 5, 1718–1726. doi:10.1021/ic062319b.
- ^ F. Bianchi; M.C. Gallazzi; L. Porri; P. Diversi (1980). Disproportionation of the cyclooctene ligand in the reaction of [IrCl(C8H14)2]2. With AgOCOCF3: formation of [Ir(OCOCF3)(C8H14)2]2 and [Ir(OCOCF3)(1,5-C8H12]2 and their conversion into cationic arene complexes. Journal of Organometallic Chemistry, 202(1), 99–105. doi:10.1016/s0022-328x(00)81387-x
- ^ F. Bianchi; M.C. Gallazzi; L. Porri; P. Diversi (1980). Disproportionation of the cyclooctene ligand in the reaction of [IrCl(C8H14)2]2. With AgOCOCF3: formation of [Ir(OCOCF3)(C8H14)2]2 and [Ir(OCOCF3)(1,5-C8H12]2 and their conversion into cationic arene complexes. Journal of Organometallic Chemistry, 202(1), 99–105. doi:10.1016/s0022-328x(00)81387-x