六氟锑酸铯

六氟锑酸铯
识别
CAS号	16949-12-5
性质
化学式	CsF6Sb
摩尔质量	368.66 g·mol−1
密度	4.11 g·cm−3
熔点	868 °C（1,141 K）（1.3 GPa）
沸点	310 °C（583 K）（常压，分解）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

六氟锑酸铯是一种无机化合物，化学式为CsSbF₆。它可由五氧化二锑和碳酸铯在过量氢氟酸中溶解制得。^[2]它是菱方晶系的晶体，空间群R3，晶胞参数a=7.904 Å，c=8.261 Å。^[1]它和[XeF₅][SbF₆]在无水氟化氢中反应，可以得到Cs[XeF₅][SbF₆]₂。^[3]六氟锑酸铯和氟化铯在300 °C反应，可以得到Cs₂[SbF₇]^[4]；它的水溶液在蒸发时发生水解，生成CsSbF₅OH^[5]。

参考文献

^ ^1.0 ^1.1 M. M. Steyn, A. M. Heyns, R. B. English. X-ray and Raman studies of single crystals of CsSbF6. Journal of Crystallographic and Spectroscopic Research. 1984-10, 14 (5): 505–512 [2021-01-07]. ISSN 0277-8068. doi:10.1007/BF01160697 （英语）.
^ ^2.0 ^2.1 ^2.2 W.H.J. de Beer, Anton M. Heyns, P.W. Richter, J.B. Clark. High-pressure/high-temperature phase relations and vibrational spectra of CsSbF6. Journal of Solid State Chemistry. 1980-07, 33 (3): 283–288 [2021-01-07]. doi:10.1016/0022-4596(80)90147-4. （原始内容存档于2018-06-08）（英语）.
^ Zoran Mazej, Evgeny Goreshnik. Crystal Growth and Characterization of the Mixed-Cation Rb + /[XeF 5 ] + and Cs + /[XeF 5 ] + Salts: Crystal Growth and Characterization of the Mixed-Cation Rb + /[XeF 5 ] + and Cs + /[XeF 5 ] + Salts. European Journal of Inorganic Chemistry. 2017-06-08, 2017 (21): 2800–2807 [2021-01-07]. doi:10.1002/ejic.201700097 （英语）.
^ Greg W. Drake, David A. Dixon, Jeffrey A. Sheehy, Jerry A. Boatz, Karl O. Christe. Seven-Coordinated Pnicogens. Synthesis and Characterization of the SbF 7 2- and BiF 7 2- Dianions and a Theoretical Study of the AsF 7 2- Dianion. Journal of the American Chemical Society. 1998-08, 120 (33): 8392–8400 [2021-01-07]. ISSN 0002-7863. doi:10.1021/ja9805728. （原始内容存档于2021-12-28）（英语）.
^ Lothar Kolditz, Walter Rehak. Über fluorhaltige Verbindungen der Elemente der V. Hauptgruppe. IX. Über monomere und kondensierte Fluoroantimonate. Zeitschrift für anorganische und allgemeine Chemie. 1959-08, 300 (5-6): 322–336 [2021-01-07]. ISSN 0044-2313. doi:10.1002/zaac.19593000512 （德语）.

[Steyn-1] 1.0 ^1.1 M. M. Steyn, A. M. Heyns, R. B. English. X-ray and Raman studies of single crystals of CsSbF6. Journal of Crystallographic and Spectroscopic Research. 1984-10, 14 (5): 505–512 [2021-01-07]. ISSN 0277-8068. doi:10.1007/BF01160697 （英语）.

[Beer-2] 2.0 ^2.1 ^2.2 W.H.J. de Beer, Anton M. Heyns, P.W. Richter, J.B. Clark. High-pressure/high-temperature phase relations and vibrational spectra of CsSbF6. Journal of Solid State Chemistry. 1980-07, 33 (3): 283–288 [2021-01-07]. doi:10.1016/0022-4596(80)90147-4. （原始内容存档于2018-06-08）（英语）.

[3] Zoran Mazej, Evgeny Goreshnik. Crystal Growth and Characterization of the Mixed-Cation Rb + /[XeF 5 ] + and Cs + /[XeF 5 ] + Salts: Crystal Growth and Characterization of the Mixed-Cation Rb + /[XeF 5 ] + and Cs + /[XeF 5 ] + Salts. European Journal of Inorganic Chemistry. 2017-06-08, 2017 (21): 2800–2807 [2021-01-07]. doi:10.1002/ejic.201700097 （英语）.

[4] Greg W. Drake, David A. Dixon, Jeffrey A. Sheehy, Jerry A. Boatz, Karl O. Christe. Seven-Coordinated Pnicogens. Synthesis and Characterization of the SbF 7 2- and BiF 7 2- Dianions and a Theoretical Study of the AsF 7 2- Dianion. Journal of the American Chemical Society. 1998-08, 120 (33): 8392–8400 [2021-01-07]. ISSN 0002-7863. doi:10.1021/ja9805728. （原始内容存档于2021-12-28）（英语）.

[5] Lothar Kolditz, Walter Rehak. Über fluorhaltige Verbindungen der Elemente der V. Hauptgruppe. IX. Über monomere und kondensierte Fluoroantimonate. Zeitschrift für anorganische und allgemeine Chemie. 1959-08, 300 (5-6): 322–336 [2021-01-07]. ISSN 0044-2313. doi:10.1002/zaac.19593000512 （德语）.

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