1-十四烯

化合物

1-十四烯(英語:1-Tetradecene)是一种有机化合物,化学式C14H28,存在于焦曲霉Aspergillus ustus[1]香莢蘭Vanilla planifolia[2]等物种中。它在光照和Pd/BiOBr/BiVO4催化下,可以被乙醇还原为正十四烷[3]

1-十四烯
英文名 1-Tetradecene
识别
CAS号 1120-36-1  checkY
PubChem 14260
ChemSpider 13622
SMILES
 
  • CCCCCCCCCCCCC=C
InChI
 
  • 1S/C14H28/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3H,1,4-14H2,2H3
InChIKey HFDVRLIODXPAHB-UHFFFAOYSA-N
ChEBI 77505
性质
化学式 C14H28
摩尔质量 196.37 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考资料

编辑
  1. ^ Oleinikova, G. K.; Slinkina, N. N.; Afiyatullov, Sh. Sh. Nonpolar compounds and free fatty acids from marine fungi Aspergillus ustus. Chemistry of Natural Compounds. 2011-11, 47 (5): 805–806. doi:10.1007/S10600-011-0066-3. 
  2. ^ Ramaroson-Raonizafinimanana, Béatrice; Gaydou, Émile M.; Bombarda, Isabelle. Hydrocarbons from Three Vanilla Bean Species: V. fragrans , V. madagascariensis , and V. tahitensis. Journal of Agricultural and Food Chemistry. 1997-07-01, 45 (7): 2542–2545. doi:10.1021/JF960927B. 
  3. ^ Miller, Edward B.; Knecht, Marc R.; Bachas, Leonidas G. Photocatalytic Approaches for Sustainable Olefin Transfer Hydrogenation and Semihydrogenation of Alkynes Using Natural Sunlight. ACS Applied Energy Materials (2022), 5(9), 11052-11057. doi:10.1021/acsaem.2c01643.