丁酸鈉
化合物
丁酸鈉是一種化合物,化學式為C3H7COONa。它可由丁酸和氫氧化鈉反應製得。[1]它和氯化苄在聚乙二醇中加熱反應,可以得到丁酸苄酯。[2]它可被溴代叔己基硼烷二甲硫醚(ThxBHBr-SMe2)[3]或9-硼二環[3.3.1]壬烷(9-BBN)[4]還原為丁醛。
丁酸鈉 | |
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IUPAC名 Sodium butanoate | |
別名 | Sodium butyrate |
識別 | |
CAS號 | 156-54-7 |
PubChem | 5222465 |
ChemSpider | 8727 |
SMILES |
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InChI |
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ChEBI | 64103 |
性質 | |
化學式 | C4H7NaO2 |
摩爾質量 | 110.09 g·mol−1 |
相關物質 | |
其他陰離子 | 丙酸鈉 戊酸鈉 |
其他陽離子 | 丁酸鋰 丁酸鉀 |
相關化學品 | 羥基丁酸鈉 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
參考文獻
編輯- ^ Qiang Huang, Qingyi Meng, Chunlan Ban, Rui Zhang, Yingyu Gao. Study of liquid–solid catalytic reaction of epichlorohydrin with sodium butyrate in the presence of tetrabutylammonium bromide. Russian Journal of Physical Chemistry A. 2016-08, 90 (8): 1552–1556 [2023-02-23]. ISSN 0036-0244. doi:10.1134/S0036024416080240 (英語).
- ^ Yu‐Qing Cao, Guo‐Qiang Wu, Ya‐Bin Li, Zhi Dai, Bao‐Hua Chen. Practical Preparation of Esters and Thioacetates from Alkyl Halides and Carboxylates or Thioacetate Catalyzed by PEG400 without Solvent. Synthetic Communications. 2006-11-01, 36 (22): 3353–3358 [2023-02-23]. ISSN 0039-7911. doi:10.1080/00397910600941380 (英語).
- ^ Jin Soon Cha, Jin Euog Kim, Kwang Woo Lee. Facile reduction of saturated and unsaturated carboxylic acids and their salts to aldehydes by thexylbromoborane-dimethyl sulfide. The Journal of Organic Chemistry. 1987-10, 52 (22): 5030–5032 [2023-02-23]. ISSN 0022-3263. doi:10.1021/jo00231a037. (原始內容存檔於2023-02-23) (英語).
- ^ Cha, Jin Soon; Oh, Se Yeon; Lee, Kwang Woo; Yoon, Mal Sook; Lee, Jae Cheol; Kim, Jin Euog. Exceptionally facile reduction of carboxylic acid salts to aldehydes by 9-borabicyclo[3.3.1]nonane. Heterocycles, 1988. 27 (7): 1595-1598.