丁酸钠
化合物
丁酸钠是一种化合物，化学式为C3H7COONa。它可由丁酸和氢氧化钠反应制得。[1]它和氯化苄在聚乙二醇中加热反应，可以得到丁酸苄酯。[2]它可被溴代叔己基硼烷二甲硫醚（ThxBHBr-SMe2）[3]或9-硼二环[3.3.1]壬烷（9-BBN）[4]还原为丁醛。
| 丁酸钠 | |
|---|---|
| |
| IUPAC名 Sodium butanoate | |
| 别名 | Sodium butyrate |
| 识别 | |
| CAS号 | 156-54-7 
|
| PubChem | 5222465 |
| ChemSpider | 8727 |
| SMILES |
|
| InChI |
|
| ChEBI | 64103 |
| 性质 | |
| 化学式 | C4H7NaO2 |
| 摩尔质量 | 110.09 g·mol−1 |
| 相关物质 | |
| 其他阴离子 | 丙酸钠 戊酸钠 |
| 其他阳离子 | 丁酸锂 丁酸钾 |
| 相关化学品 | 羟基丁酸钠 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Qiang Huang, Qingyi Meng, Chunlan Ban, Rui Zhang, Yingyu Gao. Study of liquid–solid catalytic reaction of epichlorohydrin with sodium butyrate in the presence of tetrabutylammonium bromide. Russian Journal of Physical Chemistry A. 2016-08, 90 (8): 1552–1556 [2023-02-23]. ISSN 0036-0244. doi:10.1134/S0036024416080240 （英语）.
- ^ Yu‐Qing Cao, Guo‐Qiang Wu, Ya‐Bin Li, Zhi Dai, Bao‐Hua Chen. Practical Preparation of Esters and Thioacetates from Alkyl Halides and Carboxylates or Thioacetate Catalyzed by PEG400 without Solvent. Synthetic Communications. 2006-11-01, 36 (22): 3353–3358 [2023-02-23]. ISSN 0039-7911. doi:10.1080/00397910600941380 （英语）.
- ^ Jin Soon Cha, Jin Euog Kim, Kwang Woo Lee. Facile reduction of saturated and unsaturated carboxylic acids and their salts to aldehydes by thexylbromoborane-dimethyl sulfide. The Journal of Organic Chemistry. 1987-10, 52 (22): 5030–5032 [2023-02-23]. ISSN 0022-3263. doi:10.1021/jo00231a037. （原始内容存档于2023-02-23） （英语）.
- ^ Cha, Jin Soon; Oh, Se Yeon; Lee, Kwang Woo; Yoon, Mal Sook; Lee, Jae Cheol; Kim, Jin Euog. Exceptionally facile reduction of carboxylic acid salts to aldehydes by 9-borabicyclo[3.3.1]nonane. Heterocycles, 1988. 27 (7): 1595-1598.