橙花酸

橙花酸
	IUPAC名; (2Z)-3,7-Dimethylocta-2,6-dienoic acid; (2Z)-3,7-二甲基辛-2,6-二烯酸
别名	3,7-二甲基-2,6-辛二烯酸
识别
CAS号	4613-38-1
PubChem	5275520
ChemSpider	4472008
SMILES	CC(=CCC/C(=C/C(=O)O)/C)C;
InChI	1S/C10H16O2/c1-8(2)5-4-6-9(3)7-10(11)12/h5,7H,4,6H2,1-3H3,(H,11,12)/b9-7+;
InChIKey	ZHYZQXUYZJNEHD-VQHVLOKHSA-N
EINECS	202-058-4
性质
化学式	C10H16O2
摩尔质量	168.23 g·mol−1
相关物质
相关化合物	橙花醇
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

橙花酸（英语：nerolic acid，neric acid）,别名(2Z)-3,7-二甲基辛-2,6-二烯酸，是一种不饱和羧酸，化学式：C₁₀H₁₆O₂，为橙花醇的衍生物，是一种蜜蜂信息素。

生物分布

橙花酸是在蜜蜂奈氏腺（英语：Nasonov's gland）中发现，连同香叶醇、香叶酸、柠檬醛、橙花醇、法尼醇等类萜物质一起发现，并称为奈氏腺信息素。其中又属香叶醇、法尼醇和橙花酸占比最高^[1]^[2]^[3]。

橙花酸存在于在桃金娘科植物中^[4]^[5]。如橙花酸是构成桃金娘科矾木属植物Myrcia Ovata的植物精油五种物质之一^[4] 。同时也在另一种矾木属植物Myrcia lundiana中大量发现，其具有抗真菌活性，可抗茄类镰孢（英语：Fusarium solani）菌和可可球二孢菌^[5]

此外，橙花酸同时也是香茅草精油的主要成分，并相信其同样具有抗真菌活性 ^[6]。

参考文献

^ Winston, Mark L. The Biology of the Honey Bee. First Harvard University Press. 1987: 37. ISBN 978-0-674-07409-5.
^ R Boch; DA Shearer. Identification of Nerolic and Geranic Acids in the Nassanoff Pheromone of the Honey Bee. Nature. April 18, 1964, 202 (4929): 320–321. Bibcode:1964Natur.202..320B. S2CID 4283000. doi:10.1038/202320a0.
^ Free JB, Ferguson AW, Picket JA. Evalutation of Various Components of the Nasonov Pheromone used by clustering honeybees. Physiological Entomology. 1981, 6 (3): 263–268. S2CID 86732208. doi:10.1111/j.1365-3032.1981.tb00270.x.
^ ^4.0 ^4.1 White, Larissa Alves Secundo; Blank, Arie Fitzgerald; Gagliardi, Paulo Roberto; Arrigoni-Blank, Maria de Fátima; Nizio, Daniela Aparecida de Castro; Sampaio, Taís Santos; Alves, Mércia Freita; Almeida-Pereira, Camila Santos. In vitro antifungal activity of Myrcia ovata essential oils and their major compounds against pathogens of citrus, sweet potato, and coconut. Bioscience Journal. 2019-10-15, 35 (6): 1696. ISSN 1981-3163. S2CID 213523415. doi:10.14393/BJ-v35n6a2019-42425  （英语）.
^ ^5.0 ^5.1 Alves, Mércia Freitas; Nizio, Daniela Aparecida de Castro; Sampaio, Taís Santos; Nascimento, Alberto Ferreira do; Brito, Fabiany de Andrade; Melo, Juliana Oliveira de; Arrigoni-Blank, Maria de Fátima; Gagliardi, Paulo Roberto; Machado, Samisia Maria Fernandes; Blank, Arie Fitzgerald. Myrcia lundiana Kiaersk native populations have different essential oil composition and antifungal activity against Lasiodiplodia theobromae. Industrial Crops and Products. 2016-07-01, 85: 268. ISSN 0926-6690. doi:10.1016/j.indcrop.2016.03.039 （英语）.
^ Sargenti, S. R.; Lanças, F. M. Supercritical fluid extraction ofCymbopogon citratus (DC.) Stapf. Chromatographia. 1997-09-01, 46 (5): 286. ISSN 1612-1112. S2CID 92933820. doi:10.1007/BF02496320 （英语）.

[honeybeebiology-1] Winston, Mark L. The Biology of the Honey Bee. First Harvard University Press. 1987: 37. ISBN 978-0-674-07409-5.

[2] R Boch; DA Shearer. Identification of Nerolic and Geranic Acids in the Nassanoff Pheromone of the Honey Bee. Nature. April 18, 1964, 202 (4929): 320–321. Bibcode:1964Natur.202..320B. S2CID 4283000. doi:10.1038/202320a0.

[3] Free JB, Ferguson AW, Picket JA. Evalutation of Various Components of the Nasonov Pheromone used by clustering honeybees. Physiological Entomology. 1981, 6 (3): 263–268. S2CID 86732208. doi:10.1111/j.1365-3032.1981.tb00270.x.

[:0-4] 4.0 ^4.1 White, Larissa Alves Secundo; Blank, Arie Fitzgerald; Gagliardi, Paulo Roberto; Arrigoni-Blank, Maria de Fátima; Nizio, Daniela Aparecida de Castro; Sampaio, Taís Santos; Alves, Mércia Freita; Almeida-Pereira, Camila Santos. In vitro antifungal activity of Myrcia ovata essential oils and their major compounds against pathogens of citrus, sweet potato, and coconut. Bioscience Journal. 2019-10-15, 35 (6): 1696. ISSN 1981-3163. S2CID 213523415. doi:10.14393/BJ-v35n6a2019-42425  （英语）.

[:1-5] 5.0 ^5.1 Alves, Mércia Freitas; Nizio, Daniela Aparecida de Castro; Sampaio, Taís Santos; Nascimento, Alberto Ferreira do; Brito, Fabiany de Andrade; Melo, Juliana Oliveira de; Arrigoni-Blank, Maria de Fátima; Gagliardi, Paulo Roberto; Machado, Samisia Maria Fernandes; Blank, Arie Fitzgerald. Myrcia lundiana Kiaersk native populations have different essential oil composition and antifungal activity against Lasiodiplodia theobromae. Industrial Crops and Products. 2016-07-01, 85: 268. ISSN 0926-6690. doi:10.1016/j.indcrop.2016.03.039 （英语）.

[6] Sargenti, S. R.; Lanças, F. M. Supercritical fluid extraction ofCymbopogon citratus (DC.) Stapf. Chromatographia. 1997-09-01, 46 (5): 286. ISSN 1612-1112. S2CID 92933820. doi:10.1007/BF02496320 （英语）.

[1]

[2]

[3]

[4]

[5]

[6]

橙花酸

IUPAC名 (2Z)-3,7-Dimethylocta-2,6-dienoic acid (2Z)-3,7-二甲基辛-2,6-二烯酸
别名	3,7-二甲基-2,6-辛二烯酸
识别
CAS号	4613-38-1 ^Y
PubChem	5275520
ChemSpider	4472008
SMILES	CC(=CCC/C(=C/C(=O)O)/C)C
InChI	1S/C10H16O2/c1-8(2)5-4-6-9(3)7-10(11)12/h5,7H,4,6H2,1-3H3,(H,11,12)/b9-7+
InChIKey	ZHYZQXUYZJNEHD-VQHVLOKHSA-N
EINECS	202-058-4
性质
化学式	C₁₀H₁₆O₂
摩尔质量	168.23 g·mol⁻¹
相关物质
相关化合物	橙花醇
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

橙花酸

生物分布

相关条目

参考文献