1,3,5,7-金剛烷四甲酸

化合物

1,3,5,7-金剛烷四甲酸是一種有機化合物,化學式為C14H16O8。它是一種氫鍵有機框架材料的單體[4]樹狀聚合物的原料[3]。它可由1,3,5,7-金剛烷四甲醯胺的水解製得。[5]

1,3,5,7-金剛烷四甲酸[1][2]
IUPAC名
Adamantane-1,3,5,7-tetracarboxylic acid
別名 1,3,5,7-Adamantanetetracarboxylic acid
Tricyclo[3.3.1.13,7]decane-1,3,5,7-tetracarboxylic acid
識別
縮寫 ADTA
CAS號 100884-80-8  checkY
PubChem 622495
ChemSpider 540862
SMILES
 
  • C1C2(CC3(CC1(CC(C2)(C3)C(=O)O)C(=O)O)C(=O)O)C(=O)O
性質
化學式 C14H16O8
摩爾質量 312.27 g·mol−1
外觀 無色固體[3]
熔點 395 °C(668 K)
相關物質
相關化學品 1-金剛烷甲酸
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

編輯
  1. ^ Adamantane-1,3,5,7-tetracarboxylic acid. PubChem. [18 January 2024]. (原始內容存檔於2024-01-18). 
  2. ^ 1,3,5,7-Adamantanetetracarboxylic acid. ChemSpider. [18 January 2024]. (原始內容存檔於2024-01-18). 
  3. ^ 3.0 3.1 Newkome, George R.; Nayak, Ashutosh; Behera, Rajani K.; Moorefield, Charles N.; Baker, Gregory R. Chemistry of micelles series. 22. Cascade polymers: synthesis and characterization of four-directional spherical dendritic macromolecules based on adamantane. Journal of Organic Chemistry. 1992, 57 (1): 358–362. doi:10.1021/jo00027a061. 
  4. ^ Li, Penghao; Ryder, Matthew R.; Stoddart, J. Fraser. Hydrogen-Bonded Organic Frameworks: A Rising Class of Porous Molecular Materials. Accounts of Materials Research. 2020, 1 (1): 77–87. doi:10.1021/accountsmr.0c00019. 
  5. ^ Ermer, Otto. Five-fold diamond structure of adamantane-1,3,5,7-tetracarboxylic acid. Journal of the American Chemical Society. 1988, 110 (12): 3747–3754. doi:10.1021/ja00220a005.