1,3,5,7-金刚烷四甲酸

化合物

1,3,5,7-金刚烷四甲酸是一种有机化合物,化学式为C14H16O8。它是一种氢键有机框架材料的单体[4]树状聚合物的原料[3]。它可由1,3,5,7-金刚烷四甲酰胺的水解制得。[5]

1,3,5,7-金刚烷四甲酸[1][2]
IUPAC名
Adamantane-1,3,5,7-tetracarboxylic acid
别名 1,3,5,7-Adamantanetetracarboxylic acid
Tricyclo[3.3.1.13,7]decane-1,3,5,7-tetracarboxylic acid
识别
缩写 ADTA
CAS号 100884-80-8  checkY
PubChem 622495
ChemSpider 540862
SMILES
 
  • C1C2(CC3(CC1(CC(C2)(C3)C(=O)O)C(=O)O)C(=O)O)C(=O)O
性质
化学式 C14H16O8
摩尔质量 312.27 g·mol−1
外观 无色固体[3]
熔点 395 °C(668 K)
相关物质
相关化学品 1-金刚烷甲酸
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Adamantane-1,3,5,7-tetracarboxylic acid. PubChem. [18 January 2024]. (原始内容存档于2024-01-18). 
  2. ^ 1,3,5,7-Adamantanetetracarboxylic acid. ChemSpider. [18 January 2024]. (原始内容存档于2024-01-18). 
  3. ^ 3.0 3.1 Newkome, George R.; Nayak, Ashutosh; Behera, Rajani K.; Moorefield, Charles N.; Baker, Gregory R. Chemistry of micelles series. 22. Cascade polymers: synthesis and characterization of four-directional spherical dendritic macromolecules based on adamantane. Journal of Organic Chemistry. 1992, 57 (1): 358–362. doi:10.1021/jo00027a061. 
  4. ^ Li, Penghao; Ryder, Matthew R.; Stoddart, J. Fraser. Hydrogen-Bonded Organic Frameworks: A Rising Class of Porous Molecular Materials. Accounts of Materials Research. 2020, 1 (1): 77–87. doi:10.1021/accountsmr.0c00019. 
  5. ^ Ermer, Otto. Five-fold diamond structure of adamantane-1,3,5,7-tetracarboxylic acid. Journal of the American Chemical Society. 1988, 110 (12): 3747–3754. doi:10.1021/ja00220a005.