SIB-1893

化合物

SIB-1893是一种有机化合物,化学式为C14H13N。它可由2-甲基-6-苯乙炔基吡啶和硫化钠九水合物在二甲基甲酰胺中于140 °C反应制得。[1]苯甲醛2,6-二甲基吡啶为原料在路易斯酸催化下反应,也可得到该化合物。[2]草酸二水合物的存在下,它可以发生光二聚反应,得到1,3-二苯基-2,4-二(6-甲基吡啶-2-基)环丁烷。[3]

SIB-1893
识别信息
  • (E)-2-methyl-6-(2-phenylethenyl)pyridine
CAS号7370-21-0trans checkY
6266-99-5  checkY
PubChem CID
ChemSpider
UNII
ChEMBL
CompTox Dashboard英语CompTox Chemicals Dashboard (EPA)
化学信息
化学式C14H13N
摩尔质量195.27 g·mol−1
3D模型(JSmol英语JSmol
  • c1ccccc1\C=C\c(nc2C)ccc2
  • InChI=1S/C14H13N/c1-12-6-5-9-14(15-12)11-10-13-7-3-2-4-8-13/h2-11H,1H3/b11-10+ ☒N
  • Key:SISOFUCTXZKSOQ-ZHACJKMWSA-N ☒N

参考文献

编辑
  1. ^ Zhengwang Chen, Miaoting Luo, Yuelu Wen, Guotian Luo, Liangxian Liu. Transition-Metal-Free Semihydrogenation of Diarylalkynes: Highly Stereoselective Synthesis of trans -Alkenes Using Na 2 S·9H 2 O. Organic Letters. 2014-06-06, 16 (11): 3020–3023 [2021-09-21]. ISSN 1523-7060. doi:10.1021/ol501137x. (原始内容存档于2021-09-21) (英语). 
  2. ^ Dan Mao, Gang Hong, Shengying Wu, Xin Liu, Jianjun Yu, Limin Wang. Lewis-Acid-Catalyzed Benzylic Reactions of 2-Methylazaarenes with Aldehydes: Benzylic Reactions of 2-Methylazaarenes. European Journal of Organic Chemistry. 2014-05, 2014 (14): 3009–3019 [2021-09-21]. doi:10.1002/ejoc.201400073 (英语). 
  3. ^ Thanh Binh Nguyen, Tuan Minh Nguyen, Pascal Retailleau. [2+2] Photodimerization of Stilbazoles Promoted by Oxalic Acid in Suspension. Chemistry – A European Journal. 2020-04-09, 26 (21): 4682–4689 [2021-09-21]. ISSN 0947-6539. doi:10.1002/chem.201905597 (英语).