溴二碘甲烷
化合物
溴二碘甲烷是一种有机化合物，化学式为CHBrI2。它可由三碘甲烷和溴在四氯化碳中于0 °C反应得到，产率52%。[3]它和五氯化锑反应，可以得到氯溴碘甲烷。[4]它在苄基三乙基氯化铵的存在下于氢氧化钠的浓溶液中可以形成溴碘卡宾，和烯烃反应形成三元环。[5]
| 溴二碘甲烷 | |
|---|---|
| |
| 识别 | |
| CAS号 | 557-95-9 
|
| 性质 | |
| 化学式 | CHBrI2 |
| 摩尔质量 | 346.73 g·mol−1 |
| 气味 | 甜味、药味[1] |
| 熔点 | 59 °C（332 K）[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Khiari, D. Distribution Generated Taste-and-odor Phenomena. AWWA Research Foundation and American Water Works Association. 2002: 1-PA15 [2021-11-02]. ISBN 978-1-58321-227-1. （原始内容存档于2021-11-05）.
- ^ Igor Novak, Dong Bo Li, Anthony W. Potts, Abdulla Shareef, Branka Kovač. Halogen−Halogen Interactions in Halomethanes. The Journal of Organic Chemistry. 2002-05-01, 67 (10): 3510–3513 [2021-11-02]. ISSN 0022-3263. doi:10.1021/jo011132t. （原始内容存档于2021-11-05） （英语）.
- ^ Dong Bo Li, Siu-Choon Ng, Igor Novak. Novel synthetic approaches to CHBrFI, CHClFI and CHBrClI. Tetrahedron. 2002-07, 58 (29): 5923–5926 [2021-11-02]. doi:10.1016/S0040-4020(02)00532-X （英语）.
- ^ Charette, A.B.; Aggarwal, V.K.; Aitken, R.A.; Cicchi, S.; Cordero, F. Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 22: Three Carbon-Heteroatom Bonds: Thio-, Seleno-, and Tellurocarboxylic Acids and Derivatives; Imidic Acids and Derivatives; Ortho Acid Derivatives. Thieme. 2014: 6-PA99 [2021-11-02]. ISBN 978-3-13-178151-2. （原始内容存档于2021-11-03）.
- ^ de Meijere, A.; Baird, M.S.; Bertrand, G.; de Kimpe, N.; Fedorynski, M. Houben-Weyl Methods of Organic Chemistry Vol. E 17a, 4th Edition Supplement: Carbocyclic Three-Membered Ring Compounds, Cyclopropanes: Synthesis. Thieme. 2014: 728 [2021-11-02]. ISBN 978-3-13-181944-4. （原始内容存档于2021-11-05）.