标准电极电势表
维基媒体列表条目
标准电极电势可以用来计算化学电池或原电池的电化学势或电极电势。
标准电极电位是以标准氢原子作为参比电极,即氢的标准电极电位值定为0,与氢标准电极比较,电位较高者为正,电位较低者为负。
表中电极电势以以下条件测得((s):固体;(l):液体;(g):气体;(aq):水溶液;(Hg):汞齐):
- 参比电极:标准氢电极,所有离子的数据都在水溶液测得[1][2][3][4][5][6][7][8][9]
- 活性度:统一为纯固体、纯液体或水溶液
- 温度:298.15K/25摄氏度
- 水溶液或汞齐之有效离子浓度:每公升1摩
- 气体反应物分压:1大气压/101325帕
单击顶栏箭咀可将数据按元素符号、反应物、产物或标准电极电势值排序。
元素 | 氧化剂 | 半反应 | 还原剂 | E°(V)[注 1] | 来源 |
---|---|---|---|---|---|
钡 | Ba+ +e⁻ |
⇌ | Ba(s) | −4.38 | [10][11][12] |
锶 | Sr+ +e⁻ |
⇌ | Sr(s) | −4.10 | [13][10][11][14] |
钙 | Ca+ +e⁻ |
⇌ | Ca(s) | −3.8 | [13][10][11][14] |
钍 | Th⁴⁺+e⁻ | ⇌ | Th³⁺ | −3.6 | [15] |
镨 | Pr³⁺+e⁻ | ⇌ | Pr²⁺ | −3.1 | [13] |
氮 | 3N 2(g)+2H⁺+2e⁻ |
⇌ | 2HN 3(aq) |
−3.09 | [16] |
锂 | Li+ +e⁻ |
⇌ | Li(s) | −3.0401 | [17] |
氮 | N 2(g)+4H₂O+2e⁻ |
⇌ | 2NH 2OH(aq)+2OH⁻ |
−3.04 | [16] |
铯 | Cs+ +e⁻ |
⇌ | Cs(s) | −3.026 | [17] |
钙 | Ca(OH) 2(s)+2e⁻ |
⇌ | Ca(s)+2OH⁻ | −3.02 | [13] |
铒 | Er3+ +e⁻ |
⇌ | Er2+ |
−3.0 | [13] |
钡 | Ba(OH) 2(s)+2e⁻ |
⇌ | Ba(s)+2OH⁻ | −2.99 | [13] |
铷 | Rb+ +e⁻ |
⇌ | Rb(s) | −2.98 | [18] |
钾 | K+ +e⁻ |
⇌ | K(s) | −2.92 | [17] |
镁 | Mg+ +e⁻ |
⇌ | Mg(s) | −2.93 | [12] |
钡 | Ba2+ +2e⁻ |
⇌ | Ba(s) | −2.912 | [17] |
镧 | La(OH) 3(s)+3e⁻ |
⇌ | La(s)+3OH⁻ | −2.90 | [17] |
钫 | Fr+ +e⁻ |
⇌ | Fr(s) | −2.9 | [13] |
锶 | Sr2+ +2e⁻ |
⇌ | Sr(s) | −2.899 | [17] |
锶 | Sr(OH) 2(s)+2e⁻ |
⇌ | Sr(s)+2OH⁻ | −2.88 | [13] |
钙 | Ca2+ +2e⁻ |
⇌ | Ca(s) | −2.868 | [17] |
铵 | NH+ 4+e⁻ |
⇌ | NH 4• |
−2.85 | |
铕 | Eu2+ +2e⁻ |
⇌ | Eu(s) | −2.812 | [17] |
镭 | Ra2+ +2e⁻ |
⇌ | Ra(s) | −2.8 | [17] |
镱 | Yb2+ +2e⁻ |
⇌ | Yb(s) | −2.76 | [13][10] |
钠 | Na+ +e⁻ |
⇌ | Na(s) | −2.71 | [17][19] |
钐 | Sm2+ +2e⁻ |
⇌ | Sm(s) | −2.68 | [13][10] |
锘 | No2+ +2e⁻ |
⇌ | No(s) | −2.50 | [13] |
铪 | HfO(OH) 2(s)+H₂O+4e⁻ |
⇌ | Hf(s)+4OH⁻ | −2.50 | [13] |
钍 | Th(OH) 4(s)+4e⁻ |
⇌ | Th(s)+4OH⁻ | −2.48 | [13] |
钔 | Md2+ +2e⁻ |
⇌ | Md(s) | −2.40 | [13] |
镧 | La3+ +3e⁻ |
⇌ | La(s) | −2.379 | [17] |
钇 | Y3+ +3e⁻ |
⇌ | Y(s) | −2.372 | [17] |
镁 | Mg2+ +2e⁻ |
⇌ | Mg(s) | −2.372 | [17] |
锆 | ZrO(OH) 2(s)+H₂O+4e⁻ |
⇌ | Zr(s)+4OH⁻ | −2.36 | [17] |
镨 | Pr3+ +3e⁻ |
⇌ | Pr(s) | −2.353 | [13] |
铈 | Ce3+ +3e⁻ |
⇌ | Ce(s) | −2.336 | [13] |
铒 | Er3+ +3e⁻ |
⇌ | Er(s) | −2.331 | [13] |
钬 | Ho3+ +3e⁻ |
⇌ | Ho(s) | −2.33 | [13] |
铝 | Al(OH)− 4+3e⁻ |
⇌ | Al(s)+4OH⁻ | −2.33 | |
铝 | Al(OH) 3(s)+3e⁻ |
⇌ | Al(s)+3OH⁻ | −2.31 | |
铽 | Tb3+ +3e⁻ |
⇌ | Tb(s) | −2.28 | |
氢 | H 2(g)+2e⁻ |
⇌ | 2H− |
−2.25 | |
锕 | Ac3+ +3e⁻ |
⇌ | Ac(s) | −2.20 | |
铍 | Be+ +e⁻ |
⇌ | Be(s) | −2.12 | [12] |
鉲 | Cf2+ +2e⁻ |
⇌ | Cf(s) | −2.12 | [13] |
鋂 | Am3+ +3e⁻ |
⇌ | Am(s) | −2.048 | [13] |
鉲 | Cf3+ +3e⁻ |
⇌ | Cf(s) | −1.94 | [13] |
钙 | Ca2+ +e⁻ |
⇌ | Ca+ |
−1.936 | [17][13] |
鋂 | Am2+ +2e⁻ |
⇌ | Am(s) | −1.9 | [13] |
镄 | Fm3+ +3e⁻ |
⇌ | Fm(s) | −1.89 | [13] |
铍 | Be2+ +2e⁻ |
⇌ | Be(s) | −1.85 | |
𬬻 | Rf4+ +4e⁻ |
⇌ | Rf(s) | −1.67 | [20] |
铀 | U3+ +3e⁻ |
⇌ | U(s) | −1.66 | [21] |
铝 | Al3+ +3e⁻ |
⇌ | Al(s) | −1.66 | [19] |
钛 | Ti2+ +2e⁻ |
⇌ | Ti(s) | −1.63 | [19] |
鉳 | Bk2+ +2e⁻ |
⇌ | Bk(s) | −1.6 | [13] |
锆 | ZrO 2(s)+4H⁺+4e⁻ |
⇌ | Zr(s)+2H₂O | −1.553 | [17] |
铪 | Hf4+ +4e⁻ |
⇌ | Hf(s) | −1.55 | [13] |
锆 | Zr4+ +4e⁻ |
⇌ | Zr(s) | −1.45 | [17] |
钛 | Ti3+ +3e⁻ |
⇌ | Ti(s) | −1.37 | [22] |
钛 | TiO(s)+2H⁺+2e⁻ | ⇌ | Ti(s)+H₂O | −1.31 | |
钛 | Ti 2O 3(s)+2H⁺+2e⁻ |
⇌ | 2TiO(s)+H₂O | −1.23 | |
锌 | Zn(OH)2− 4+2e⁻ |
⇌ | Zn(s)+4OH⁻ | −1.199 | [23] |
锰 | Mn2+ +2e⁻ |
⇌ | Mn(s) | −1.185 | [23] |
铁 | Fe(CN)4− 6+6H⁺+2e⁻ |
⇌ | Fe(s)+6HCN(aq) | −1.16 | [24] |
钒 | V2+ +2e⁻ |
⇌ | V(s) | −1.175 | [25] |
碲 | Te(s)+2e⁻ | ⇌ | Te²⁻ | −1.143 | [25] |
铌 | Nb3+ +3e⁻ |
⇌ | Nb(s) | −1.099 | |
锡 | Sn(s)+4H⁺+4e⁻ | ⇌ | SnH 4(g) |
−1.07 | |
铟 | In(OH) 3(s)+3e⁻ |
⇌ | In(s)+3OH⁻ | −0.99 | [13] |
矽 | SiO 2(s)+4H⁺+4e⁻ |
⇌ | Si(s)+2H₂O | −0.91 | |
硼 | B(OH) 3(aq)+3H⁺+3e⁻ |
⇌ | B(s)+3H₂O | −0.89 | |
铁 | Fe(OH) 2(s)+2e⁻ |
⇌ | Fe(s)+2OH⁻ | −0.89 | [24] |
铁 | Fe₂O₃(s)+3H₂O+2e⁻ | ⇌ | 2Fe(OH) 2(s)+2OH⁻ |
−0.86 | [24] |
钛 | TiO2+ +2H⁺+4e⁻ |
⇌ | Ti(s)+H₂O | −0.86 | |
氢 | 2H₂O+2e⁻ | ⇌ | H 2(g)+2OH⁻ |
−0.8277 | [17] |
铋 | Bi(s)+3H⁺+3e⁻ | ⇌ | BiH 3 |
−0.8 | [23] |
锌 | Zn2+ +2e⁻ |
⇌ | Zn(Hg) | −0.7628 | [17] |
锌 | Zn2+ +2e⁻ |
⇌ | Zn(s) | −0.7618 | [17] |
钽 | Ta 2O 5(s)+10H⁺+10e⁻ |
⇌ | 2Ta(s)+5H₂O | −0.75 | |
铬 | Cr3+ +3e⁻ |
⇌ | Cr(s) | −0.74 | |
金 | [Au(CN)− 2]+e⁻ |
⇌ | Au(s)+2CN− |
−0.60 | |
钽 | Ta3+ +3e⁻ |
⇌ | Ta(s) | −0.6 | |
铅 | PbO(s)+H₂O+2e⁻ | ⇌ | Pb(s)+2OH⁻ | −0.58 | |
钛 | 2TiO 2(s)+2H⁺+2e⁻ |
⇌ | Ti 2O 3(s)+H₂O |
−0.56 | |
镓 | Ga3+ +3e⁻ |
⇌ | Ga(s) | −0.53 | |
铀 | U4+ +e⁻ |
⇌ | U3+ |
−0.52 | [21] |
磷 | H 3PO 2(aq)+H⁺+e⁻ |
⇌ | P(白)[26]+2H₂O | −0.508 | [17] |
磷 | H 3PO 3(aq)+2H⁺+2e⁻ |
⇌ | H 3PO 2(aq)+H₂O |
−0.499 | [17] |
磷 | H 3PO 3(aq)+3H⁺+3e⁻ |
⇌ | P(红)[26]+3H₂O | −0.454 | [17] |
铁 | Fe2+ +2e⁻ |
⇌ | Fe(s) | −0.44 | [19] |
碳 | 2CO 2(g)+2H⁺+2e⁻ |
⇌ | (HO₂C)₂(aq) | −0.43 | |
铬 | Cr3+ +e⁻ |
⇌ | Cr2+ |
−0.42 | |
镉 | Cd2+ +2e⁻ |
⇌ | Cd(s) | −0.40 | [19] |
硒 | SeO2− 3+4e⁻+3H₂O |
⇌ | Se+6OH⁻ | −0.37 | [27] |
锗 | GeO 2(s)+2H⁺+2e⁻ |
⇌ | GeO(s)+H₂O | −0.37 | |
铜 | Cu 2O(s)+H₂O+2e⁻ |
⇌ | 2Cu(s)+2OH⁻ | −0.360 | [17] |
铅 | PbSO 4(s)+2e⁻ |
⇌ | Pb(s)+SO2− 4 |
−0.3588 | [17] |
铅 | PbSO 4(s)+2e⁻ |
⇌ | Pb(Hg)+SO2− 4 |
−0.3505 | [17] |
铕 | Eu3+ +e⁻ |
⇌ | Eu2+ |
−0.35 | [21] |
铟 | In3+ +3e⁻ |
⇌ | In(s) | −0.34 | [25] |
铊 | Tl+ +e⁻ |
⇌ | Tl(s) | −0.34 | [25] |
硼 | B3+ +3e⁻ |
⇌ | B(s) | −0.31 | |
锗 | Ge(s)+4H⁺+4e⁻ | ⇌ | GeH 4(g) |
−0.29 | |
钴 | Co2+ +2e⁻ |
⇌ | Co(s) | −0.28 | [17] |
磷 | H 3PO 4(aq)+2H⁺+2e⁻ |
⇌ | H 3PO 3(aq)+H₂O |
−0.276 | [17] |
钒 | V3+ +e⁻ |
⇌ | V2+ |
−0.26 | [19] |
镍 | Ni2+ +2e⁻ |
⇌ | Ni(s) | −0.25 | |
砷 | As(s)+3H⁺+3e⁻ | ⇌ | AsH 3(g) |
−0.23 | [25] |
银 | AgI(s)+e⁻ | ⇌ | Ag(s)+I− |
−0.15224 | [23] |
钼 | MoO 2(s)+4H⁺+4e⁻ |
⇌ | Mo(s)+2H₂O | −0.15 | |
硅 | Si(s)+4H⁺+4e⁻ | ⇌ | SiH 4(g) |
−0.14 | |
锡 | Sn2+ +2e⁻ |
⇌ | Sn(s) | −0.13 | |
氧 | O 2(g)+H⁺+e⁻ |
⇌ | HO 2•(aq) |
−0.13 | |
铅 | Pb2+ +2e⁻ |
⇌ | Pb(s) | −0.13 | [19] |
钨 | WO 2(s)+4H⁺+4e⁻ |
⇌ | W(s)+2H₂O | −0.12 | |
磷 | P(红)+3H⁺+3e⁻ | ⇌ | PH 3(g) |
−0.111 | [17] |
碳 | CO 2(g)+2H⁺+2e⁻ |
⇌ | HCOOH(aq) | −0.11 | |
硒 | Se(s)+2H⁺+2e⁻ | ⇌ | H 2Se(g) |
−0.11 | |
碳 | CO 2(g)+2H⁺+2e⁻ |
⇌ | CO(g)+H₂O | −0.11 | |
锡 | SnO(s)+2H⁺+2e⁻ | ⇌ | Sn(s)+H₂O | −0.10 | |
锡 | SnO 2(s)+2H⁺+2e⁻ |
⇌ | SnO(s)+H₂O | −0.09 | |
钨 | WO 3(aq)+6H⁺+6e⁻ |
⇌ | W(s)+3H₂O | −0.09 | [25] |
磷 | P(白)+3H⁺+3e⁻ | ⇌ | PH 3(g) |
−0.063 | [17] |
氘 | 2D+ +2e⁻ |
⇌ | D 2(g) |
−0.044 | |
铁 | Fe3+ +3e⁻ |
⇌ | Fe(s) | −0.04 | [24] |
碳(甲酸) | HCO₂H(aq)+2H⁺+2e⁻ | ⇌ | HCHO(aq)+H₂O | −0.03 | |
氢 | 2H⁺+2e⁻ | ⇌ | H 2(g) |
−0.00 | ≡0 |
银 | AgBr(s)+e⁻ | ⇌ | Ag(s)+Br⁻ | +0.07133 | [23] |
硫 | S 4O2− 6+2e⁻ |
⇌ | 2S 2O2− 3 |
+0.08 | |
铁 | Fe 3O 4(s)+8H⁺+8e⁻ |
⇌ | 3Fe(s)+4H₂O | +0.085 | [28] |
氮 | N 2(g)+2H₂O+6H⁺+6e⁻ |
⇌ | 2NH 4OH(aq) |
+0.092 | |
汞 | HgO(s)+H₂O+2e⁻ | ⇌ | Hg(l)+2OH⁻ | +0.0977 | |
铜 | Cu(NH 3)2+ 4+e⁻ |
⇌ | Cu(NH 3)+ 2+2NH 3 |
+0.10 | [25] |
钌 | Ru(NH₃)₆³⁺+e⁻ | ⇌ | Ru(NH₃)₆²⁺ | +0.10 | [21] |
肼 | N 2H 4(aq)+4H₂O+2e⁻ |
⇌ | 2NH+ 4+4OH⁻ |
+0.11 | [16] |
钼 | H 2MoO 4(aq)+6H⁺+6e⁻ |
⇌ | Mo(s)+4H₂O | +0.11 | |
锗 | Ge4+ +4e⁻ |
⇌ | Ge(s) | +0.12 | |
碳 | C(s)+4H⁺+4e⁻ | ⇌ | CH 4(g) |
+0.13 | [25] |
碳 | HCHO(aq)+2H⁺+2e⁻ | ⇌ | CH 3OH(aq) |
+0.13 | |
硫 | S(s)+2H⁺+2e⁻ | ⇌ | H 2S(g) |
+0.14 | |
锡 | Sn4+ +2e⁻ |
⇌ | Sn2+ |
+0.15 | |
铜 | Cu2+ +e⁻ |
⇌ | Cu+ |
+0.159 | [25] |
硫 | HSO− 4+3H⁺+2e⁻ |
⇌ | SO 2(aq)+2H₂O |
+0.16 | |
铀 | UO2+ 2+e⁻ |
⇌ | UO+ 2 |
+0.163 | [21] |
硫 | SO2− 4+4H⁺+2e⁻ |
⇌ | SO 2(aq)+2H₂O |
+0.17 | |
钛 | TiO2+ +2H⁺+e⁻ |
⇌ | Ti3++H₂O | +0.19 | |
铋 | Bi3+ +2e⁻ |
⇌ | Bi+ | +0.2 | |
锑 | SbO+ +2H⁺+3e⁻ |
⇌ | Sb(s)+H₂O | +0.20 | |
碳 | CO 2(g)+4H⁺+4e⁻ |
⇌ | C(s)+2H₂O | +0.205 | |
银 | AgCl(s)+e⁻ | ⇌ | Ag(s)+Cl− |
+0.22233 | [23] |
砷 | H 3AsO 3(aq)+3H⁺+3e⁻ |
⇌ | As(s)+3H₂O | +0.24 | |
锗 | GeO(s)+2H⁺+2e⁻ | ⇌ | Ge(s)+H₂O | +0.26 | |
铀 | UO+ 2+4H⁺+e⁻ |
⇌ | U4+ +2H₂O |
+0.273 | [21] |
砹 | At 2+e⁻ |
⇌ | 2At− |
+0.3 | [13] |
铼 | Re3+ +3e⁻ |
⇌ | Re(s) | +0.300 | |
铋 | Bi3+ +3e⁻ |
⇌ | Bi(s) | +0.32 | |
钒 | VO2+ +2H⁺+e⁻ |
⇌ | V3+ +H₂O |
+0.34 | |
铜 | Cu2+ +2e⁻ |
⇌ | Cu(s) | +0.340 | [25] |
铁氰 | [Fe(CN) 6]3− +e⁻ |
⇌ | [Fe(CN)₆]₄⁻ | +0.36 | |
𨱏 | Tc2+ +2e⁻ |
⇌ | Tc(s) | +0.40 | [13] |
氧 | O 2(g)+2H₂O+4e⁻ |
⇌ | 4OH⁻(aq) | +0.40 | [19] |
钼 | H 2MoO 4+6H⁺+3e⁻ |
⇌ | Mo3+ +2H₂O |
+0.43 | |
钌 | Ru2+ +2e⁻ |
⇌ | Ru(s) | +0.455 | [13] |
铋 | Bi+ +e⁻ |
⇌ | Bi(s) | +0.50 | |
碳 | CH 3OH(aq)+2H⁺+2e⁻ |
⇌ | CH 4(g)+H₂O |
+0.50 | |
硫 | SO 2(aq)+4H⁺+4e⁻ |
⇌ | S(s)+2H₂O | +0.50 | |
铜 | Cu+ +e⁻ |
⇌ | Cu(s) | +0.520 | [25] |
碳 | CO(g)+2H⁺+2e⁻ | ⇌ | C(s)+H₂O | +0.52 | |
碘 | I− 3+2e⁻ |
⇌ | 3I− |
+0.53 | [19] |
碘 | I 2(s)+2e⁻ |
⇌ | 2I− |
+0.54 | [19] |
金 | [AuI− 4]+3e⁻ |
⇌ | Au(s)+4I− |
+0.56 | |
砷 | H 3AsO 4(aq)+2H⁺+2e⁻ |
⇌ | H 3AsO 3(aq)+H₂O |
+0.56 | |
金 | [AuI 2]− +e⁻ |
⇌ | Au(s)+2I− |
+0.58 | |
锰 | MnO− 4+2H₂O+3e⁻ |
⇌ | MnO 2(s)+4OH⁻ |
+0.59 | |
铑 | Rh+ +e⁻ |
⇌ | Rh(s) | +0.600 | [13] |
硫 | S 2O2− 3+6H⁺+4e⁻ |
⇌ | 2S(s)+3H₂O | +0.60 | |
铁(二茂铁) | Fe(C 5H 5) 2+e⁻ |
⇌ | Fe(C 5H 5) 2(s) |
+0.641 | [29] |
银 | CH₃CO₂Ag+e⁻ | ⇌ | Ag+CH₃CO₂⁻ | +0.643 | [13] |
钼 | H 2MoO 4(aq)+2H⁺+2e⁻ |
⇌ | MoO 2(s)+2H₂O |
+0.65 | |
苯醌 | ![]() |
⇌ | ![]() |
+0.6992 | [23] |
氧 | O 2(g)+2H⁺+2e⁻ |
⇌ | H 2O 2(aq) |
+0.70 | |
铊 | Tl3+ +3e⁻ |
⇌ | Tl(s) | +0.72 | |
铂氯 | PtCl2− 6+2e⁻ |
⇌ | PtCl2− 4+2Cl− |
+0.726 | [21] |
硒 | H 2SeO 3(aq)+4H⁺+4e⁻ |
⇌ | Se(s)+3H₂O | +0.74 | |
铑 | Rh3+ +3e⁻ |
⇌ | Rh(s) | +0.758 | [13] |
铂 | PtCl2− 4+2e⁻ |
⇌ | Pt(s)+4Cl− |
+0.758 | [21] |
铁 | Fe3+ +e⁻ |
⇌ | Fe2+ |
+0.77 | |
银 | Ag+ +e⁻ |
⇌ | Ag(s) | +0.7996 | [17] |
汞 | Hg2+ 2+2e⁻ |
⇌ | 2Hg(l) | +0.80 | |
氮(硝) | NO− 3(aq)+2H⁺+e⁻ |
⇌ | NO 2(g)+H₂O |
+0.80 | |
铁 | FeO2− 4+5H₂O+6e⁻ |
⇌ | Fe 2O 3(s)+10OH⁻ |
+0.81 | [24] |
金 | [AuBr 4]− +3e⁻ |
⇌ | Au(s)+4Br− |
+0.85 | |
汞 | Hg2+ +2e⁻ |
⇌ | Hg(l) | +0.85 | |
锰 | MnO− 4+H⁺+e⁻ |
⇌ | HMnO− 4 |
+0.90 | |
汞 | 2Hg2+ +2e⁻ |
⇌ | Hg2+ 2 |
+0.91 | [25] |
钯 | Pd2+ +2e⁻ |
⇌ | Pd(s) | +0.915 | [21] |
金 | [AuCl 4]− +3e⁻ |
⇌ | Au(s)+4Cl− |
+0.93 | |
锰 | MnO 2(s)+4H⁺+e⁻ |
⇌ | Mn3+ +2H₂O |
+0.95 | |
金 | [AuBr 2]− +e⁻ |
⇌ | Au(s)+2Br− |
+0.96 | |
氙 | [HXeO 6]3− +2H₂O+2e⁻ |
⇌ | [HXeO 4]− +4OH⁻ |
+0.99 | [30] |
氮(硝) | HNO 2+H⁺+e⁻ |
⇌ | NO(g)+H₂O | +0.996 | |
碲 | H 6TeO 6(aq)+2H⁺+2e⁻ |
⇌ | TeO 2(s)+4H₂O |
+1.02 | [31] |
溴 | Br 2(l)+2e⁻ |
⇌ | 2Br− |
+1.065 | |
溴 | Br 2(aq)+2e⁻ |
⇌ | 2Br− |
+1.087 | [19] |
氮(硝) | NO 2(g)+H⁺+e⁻ |
⇌ | HNO 2 |
+1.093 | |
碘 | IO− 3+5H⁺+4e⁻ |
⇌ | HIO(aq)+2H₂O | +1.13 | |
[AuCl− 2]+e⁻ |
⇌ | Au(s)+2Cl− |
+1.15 | ||
硒 | HSeO− 4+3H⁺+2e⁻ |
⇌ | H 2SeO 3(aq)+H₂O |
+1.15 | |
铱 | Ir3+ +3e⁻ |
⇌ | Ir(s) | +1.156 | [13] |
银 | Ag 2O(s)+2H⁺+2e⁻ |
⇌ | 2Ag(s)+H₂O | +1.17 | |
氯 | ClO− 3+2H⁺+e⁻ |
⇌ | ClO 2(g)+H₂O |
+1.18 | |
氙 | [HXeO 6]3− +5H₂O+8e⁻ |
⇌ | Xe(g)+11OH⁻ | +1.18 | [30] |
铂 | Pt2+ +2e⁻ |
⇌ | Pt(s) | +1.188 | [21] |
氯 | ClO 2(g)+H⁺+e⁻ |
⇌ | HClO 2(aq) |
+1.19 | |
碘 | 2IO− 3+12H⁺+10e⁻ |
⇌ | I 2(s)+6H₂O |
+1.20 | |
氯 | ClO− 4+2H⁺+2e⁻ |
⇌ | ClO− 3+H₂O |
+1.20 | |
氧 | O 2(g)+4H⁺+4e⁻ |
⇌ | 2H₂O | +1.229 | [19] |
锰 | MnO 2(s)+4H⁺+2e⁻ |
⇌ | Mn2+ +2H₂O |
+1.23 | |
氙 | [HXeO 4]− +3H₂O+6e⁻ |
⇌ | Xe(g)+7OH⁻ | +1.24 | [30] |
铊 | Tl3+ +2e⁻ |
⇌ | Tl+ |
+1.25 | |
铬 | Cr 2O2− 7+14H⁺+6e⁻ |
⇌ | 2Cr3+ +7H₂O |
+1.33 | |
氯 | Cl 2(g)+2e⁻ |
⇌ | 2Cl− |
+1.36 | [19] |
钴 | CoO 2(s)+4H⁺+e⁻ |
⇌ | Co3+ +2H₂O |
+1.42 | |
2NH3OH+ +H⁺+2e⁻ |
⇌ | N 2H+ 5+2H₂O |
+1.42 | [16] | |
碘 | 2HIO(aq)+2H⁺+2e⁻ | ⇌ | I 2(s)+2H₂O |
+1.44 | |
铈 | Ce4+ +e⁻ |
⇌ | Ce3+ |
+1.44 | |
溴 | BrO− 3+5H⁺+4e⁻ |
⇌ | HBrO(aq)+2H₂O | +1.45 | |
铅 | β-PbO 2(s)+4H⁺+2e⁻ |
⇌ | Pb2+ +2H₂O |
+1.460 | [25] |
铅 | α-PbO 2(s)+4H⁺+2e⁻ |
⇌ | Pb2+ +2H₂O |
+1.468 | [25] |
溴 | 2BrO− 3+12H⁺+10e⁻ |
⇌ | Br 2(l)+6H₂O |
+1.48 | |
氯 | 2ClO− 3+12H⁺+10e⁻ |
⇌ | Cl 2(g)+6H₂O |
+1.49 | |
氧(超氧) | HO 2+H⁺+e⁻ |
⇌ | H 2O 2 |
+1.495 | [13] |
锰 | MnO− 4+8H⁺+5e⁻ |
⇌ | Mn2+ +4H₂O |
+1.51 | |
HO 2•+H⁺+e⁻ |
⇌ | H 2O 2(aq) |
+1.51 | ||
金 | Au3+ +3e⁻ |
⇌ | Au(s) | +1.52 | |
镍 | NiO 2(s)+4H⁺+2e⁻ |
⇌ | Ni2+ +2OH⁻ |
+1.59 | |
氯 | HClO(aq)+2H⁺+2e⁻ | ⇌ | Cl 2(g)+2H₂O |
+1.63 | |
银 | Ag 2O 3(s)+6H⁺+4e⁻ |
⇌ | 2Ag+ +3H₂O |
+1.67 | |
氯 | HClO 2(aq)+2H⁺+2e⁻ |
⇌ | HClO(aq)+H₂O | +1.67 | |
铅 | Pb4+ +2e⁻ |
⇌ | Pb2+ |
+1.69 | [25] |
锰 | MnO− 4+4H⁺+3e⁻ |
⇌ | MnO 2(s)+2H₂O |
+1.70 | |
银 | AgO(s)+2H⁺+e⁻ | ⇌ | Ag+ +H₂O |
+1.77 | |
氧(过氧) | H 2O 2(aq)+2H⁺+2e⁻ |
⇌ | 2H₂O | +1.776 | |
钴 | Co3+ +e⁻ |
⇌ | Co2+ |
+1.82 | |
金 | Au+ +e⁻ |
⇌ | Au(s) | +1.83 | [25] |
溴 | BrO− 4+2H⁺+2e⁻ |
⇌ | BrO− 3+H₂O |
+1.85 | |
银 | Ag2+ +e⁻ |
⇌ | Ag+ |
+1.98 | [25] |
氧(过氧) | S 2O2− 8+2e⁻ |
⇌ | 2SO2− 4 |
+2.07 | |
氧 | O 3(g)+2H⁺+2e⁻ |
⇌ | O 2(g)+H₂O |
+2.075 | [21] |
锰 | HMnO− 4+3H⁺+2e⁻ |
⇌ | MnO 2(s)+2H₂O |
+2.09 | |
氙 | XeO 3(aq)+6H⁺+6e⁻ |
⇌ | Xe(g)+3H₂O | +2.12 | [30] |
氧(氟氧) | OF₂+2H⁺+4e⁻ | ⇌ | 2F− +H₂O |
+2.153 | [13] |
氙 | H 4XeO 6(aq)+8H⁺+8e⁻ |
⇌ | Xe(g)+6H₂O | +2.18 | [30] |
铁 | FeO2− 4+8H⁺+3e⁻ |
⇌ | Fe3+ +4H₂O |
+2.20 | [32] |
氙 | XeF 2(aq)+2H⁺+2e⁻ |
⇌ | Xe(g)+2HF(aq) | +2.32 | [30] |
氙 | H 4XeO 6(aq)+2H⁺+2e⁻ |
⇌ | XeO 3(aq)+H₂O |
+2.42 | [30] |
氟 | F 2(g)+2e⁻ |
⇌ | 2F− | +2.87 | [25][19] |
氟 | F 2(g)+2H⁺+2e⁻ |
⇌ | 2HF(aq) | +3.05 | [25] |
铽 | Tb4+ +e⁻ |
⇌ | Tb3+ |
+3.05 | [13] |
参见
编辑参考资料
编辑- ^ Milazzo, G., Caroli, S., and Sharma, V. K. (1978). Tables of Standard Electrode Potentials (Wiley, Chichester).
- ^ Bard, A. J., Parsons, R., and Jordan, J. (1985). Standard Potentials in Aqueous Solutions (Marcel Dekker, New York).
- ^ Bratsch, S. G. (1989). Journal of Physical Chemistry Reference Data Vol. 18, pp. 1–21.
- ^ Vanýsek, Petr (2006). "Electrochemical Series," in Handbook of Chemistry and Physics: 87th Edition (页面存档备份,存于互联网档案馆) (Chemical Rubber Company).
- ^ Vanýsek, Petr (2007). “Electrochemical Series” (页面存档备份,存于互联网档案馆), in Handbook of Chemistry and Physics: 88th Edition (页面存档备份,存于互联网档案馆) (Chemical Rubber Company).
- ^ Greenwood, N. N.; Earnshaw, A. Chemistry of the Elements 2nd. Oxford:Butterworth-Heinemann. 1997. ISBN 0-7506-3365-4.
- ^ Bard, A.J., Faulkner, L.R.(2001). Electrochemical Methods. Fundamentals and Applications, 2nd edition (John Wiley and Sons Inc).
- ^ Marcel Pourbaix (1966). Atlas of Electrochemical Equilibria in Aqueous Solutions (NACE International, Houston, Texas; Cebelcor, Brussels).
- ^ Peter Atkins (1997). Physical Chemistry, 6th edition (W.H. Freeman and Company, New York).
- ^ 10.0 10.1 10.2 10.3 10.4 Milazzo, G., Caroli, S., and Sharma, V. K. (1978). Tables of Standard Electrode Potentials (Wiley, Chichester).
- ^ 11.0 11.1 11.2 Bratsch, S. G. (1989). Journal of Physical Chemistry Reference Data Vol. 18, pp. 1–21.
- ^ 12.0 12.1 12.2 Ca Sr Ba一价[11]与两价间的标准电极电势正好有规律关系,因此可以估计近似值
- ^ 13.00 13.01 13.02 13.03 13.04 13.05 13.06 13.07 13.08 13.09 13.10 13.11 13.12 13.13 13.14 13.15 13.16 13.17 13.18 13.19 13.20 13.21 13.22 13.23 13.24 13.25 13.26 13.27 13.28 13.29 13.30 13.31 13.32 13.33 13.34 13.35 13.36 Standard Redox Potential Table. [2012-01-14]. (原始内容存档于2021-02-06).
- ^ 14.0 14.1 Lide, David R. (编), CRC Handbook of Chemistry and Physics 87th, Boca Raton, FL: CRC Press, 2006, ISBN 0-8493-0487-3
- ^ Greenwood and Earnshaw, p. 1263
- ^ 16.0 16.1 16.2 16.3 Greenwood, N. N.; Earnshaw, A. Chemistry of the Elements 2nd. Oxford:Butterworth-Heinemann. 1997. ISBN 0-7506-3365-4.
- ^ 17.00 17.01 17.02 17.03 17.04 17.05 17.06 17.07 17.08 17.09 17.10 17.11 17.12 17.13 17.14 17.15 17.16 17.17 17.18 17.19 17.20 17.21 17.22 17.23 17.24 17.25 17.26 17.27 17.28 17.29 17.30 Vanýsek, Petr (2007). “Electrochemical Series” (页面存档备份,存于互联网档案馆), in Handbook of Chemistry and Physics: 88th Edition (页面存档备份,存于互联网档案馆) (Chemical Rubber Company).
- ^ Vanýsek, Petr (2006). "Electrochemical Series," in Handbook of Chemistry and Physics: 87th Edition (页面存档备份,存于互联网档案馆) (Chemical Rubber Company).
- ^ 19.00 19.01 19.02 19.03 19.04 19.05 19.06 19.07 19.08 19.09 19.10 19.11 19.12 19.13 Peter Atkins (1997). Physical Chemistry, 6th edition (W.H. Freeman and Company, New York).
- ^ Ti Zr Hf 的标准电极电势变化较规律,因此可估计 Rf的标准电极电势
- ^ 21.00 21.01 21.02 21.03 21.04 21.05 21.06 21.07 21.08 21.09 21.10 Bard, A.J., Faulkner, L.R.(2001). Electrochemical Methods. Fundamentals and Applications, 2nd edition (John Wiley and Sons Inc).
- ^ Gordon Aylward & Tristan Findlay (2008). "SI Chemical Data", 6th edition (John Wiley & Sons, Australia), ISBN 9780470816387.
- ^ 23.0 23.1 23.2 23.3 23.4 23.5 23.6 Vanýsek, Petr (2007). “Electrochemical Series”, in Handbook of Chemistry and Physics: 88th Edition (Chemical Rubber Company).
- ^ 24.0 24.1 24.2 24.3 24.4 WebElements Periodic Table of the Elements | Iron | compounds information. [2012-01-14]. (原始内容存档于2021-01-18).
- ^ 25.00 25.01 25.02 25.03 25.04 25.05 25.06 25.07 25.08 25.09 25.10 25.11 25.12 25.13 25.14 25.15 25.16 25.17 25.18 Bard, A. J., Parsons, R., and Jordan, J. (1985). Standard Potentials in Aqueous Solutions (Marcel Dekker, New York).
- ^ 26.0 26.1 由−0.454和(2×−0.499+−0.508)÷3=−0.502推算出。
- ^ “Glyoxal Bisulfite” (页面存档备份,存于互联网档案馆), Organic Syntheses, Collected Volume 3, p.438 (1955).
- ^ Marcel Pourbaix (1966). Atlas of Electrochemical Equilibria in Aqueous Solutions (NACE International, Houston, Texas; Cebelcor, Brussels).
- ^ Connelly, Neil G.; Geiger, William E. Chemical Redox Agents for Organometallic Chemistry. Chemical Reviews. 1 January 1996, 96 (2): 877–910. PMID 11848774. doi:10.1021/cr940053x.
- ^ 30.0 30.1 30.2 30.3 30.4 30.5 30.6 WebElements Periodic Table of the Elements | Xenon | compounds information. [2012-01-14]. (原始内容存档于2021-03-22).
- ^ Cotton, F. Albert; Wilkinson, Geoffrey; Murillo, Carlos A.; Bochmann, Manfred, Advanced Inorganic Chemistry 6th, New York: Wiley-Interscience, 1999, ISBN 0-471-19957-5
- ^ Redox Reactions, Western Oregon University website. [2012-01-15]. (原始内容存档于2019-08-30).